Research Article 
A new cation induced chain-like complex [Cu(H2tea)(H2O)(imi)][Cu(H3tea)(imi)][Na
Mo8O26
]
· 4H2O
Yanyan Yang, Lin Xu, Guanggang Gao, Fengyan Li and Xizheng Liu
Journal of Coordination Chemistry, 2009, 62(16), 2583-2590. DOI: 10.1080/00958970902874276
Abstract
A new complex [Cu(H2tea)(H2O)(imi)][Cu(H3tea)(imi)][Na
Mo8O26
] · 4H2O (H3tea =triethanolamine, imi = imidazole) has been synthesized in aqueous solution and characterized by elemental analysis, IR spectroscopy, thermal gravimetric analysis, and single-crystal X-ray diffraction. X-ray diffraction reveals that β-[Mo8O26]4- polyanions are linked by sodium ions to form a chain. The coppers are five- and six-coordinate for [Cu(H3tea)(imi)]2+ and [Cu(H2O)(H2tea)(imi)]+, respectively. Crystal packing is due to hydrogen bonds and π ··· π stacking interactions, giving a 3-D polymeric network. The magnetic properties of the title compound are also presented.
ASCI-ID: 103-426
Similar Articles
Synthesis and crystal structures of two metal-nitroxide complexes including a phenanthroline-substituted nitroxide radical
Journal of Coordination Chemistry, 2008, 61(15), 2413-2421.
A new double asymmetric μ1,1-azido bridged binuclear copper(II) complex: crystal structure and magnetic propertiesJournal of Coordination Chemistry, 2008, 61(6), 900-906. DOI: 10.1080/00958970701413268
Solvent-controlled synthesis and crystal structures of a pair of azido-bridged copper(II) complexes constructed from 1-[(3-dimethylaminopropylimino)methyl]naphthalen-2-olJournal of Coordination Chemistry, 2008, 61(20), 3297-3305. DOI: 10.1080/00958970802044145
Synthesis and characterization of metal complexes of 3-( N -phenyl)-thiourea-pentanone-2Journal of Coordination Chemistry, 2008, 61(22), 3687-3692. DOI: 10.1080/00958970802123477
Synthesis, characterization, crystal structure and non-isothermal dehydration kinetics of a copper(II) complexJournal of Coordination Chemistry, 2008, 61(21), 3493-3500. DOI: 10.1080/00958970802074548
Synthesis, crystal structure and magnetism of a one-dimensional Cu(II) coordination polymer with monodeprotonated 2,2’-bypyridine-3,3’-diol as bridging ligandJournal of Coordination Chemistry, 2008, 61(21), 3501-3507. DOI: 10.1080/00958970802074563
A dinuclear diamagnetic copper(II) complex [Cu2(ophen)2]Cl2 with hydroxylated phenJournal of Coordination Chemistry, 2008, 61(24), 4033-4039. DOI: 10.1080/00958970802206785
Syntheses and crystal structures of two copper(II) complexes derived from 2-bromo-4-chloro-6-[(2-morpholin-4-ylethylimino)methyl]phenolJournal of Coordination Chemistry, 2009, 62(4), 593-599. DOI: 10.1080/00958970802307864
Syntheses and crystal structures of two Schiff-base copper(II) complexes with urease inhibitionJournal of Coordination Chemistry, 2009, 62(13), 2164-2171. DOI: 10.1080/00958970902801493
Synthesis and crystal structures of the chelating ligand 3-[(2,6-dimethylphenyl)hydrazono]-1,1,1-trifluoropentane-2,4-dione and its complex with copper(II)Journal of Coordination Chemistry, 2009, 62(21), 3401-3410. DOI: 10.1080/00958970903108070
Syntheses and crystal structures of nickel(II), copper(II), and zinc(II) complexes with a biphenyl-bridged bis(pyrrole-2-yl-methyleneamine) ligandJournal of Coordination Chemistry, 2009, 62(21), 3478-3487. DOI: 10.1080/00958970903118061
Synthesis, crystal structure, and magnetism of a binuclear Cu(II) complex with double azido as asymmetric basal-apical end-on bridged ligandJournal of Coordination Chemistry, 2010, 63(9), 1531-1537. DOI: 10.1080/00958972.2010.482667
High nuclease activity of a copper(II)-bipyridyl complex containing cytosine pendantsJournal of Coordination Chemistry, 2010, 63(14), 2440-2449. DOI: 10.1080/00958972.2010.492216
Synthesis, characterization, and crystal structure of a copper(II) complex of 1,10-phenanthroline and succinateJournal of Coordination Chemistry, 2011, 64(13), 2353-2360. DOI: 10.1080/00958972.2011.595789
Syntheses, crystal structures, and spectral characterization of two new Cu(II) and Co(II) complexes with an asymmetrical substituted triaryltriazoleJournal of Coordination Chemistry, 2011, 64(22), 3980-3991. DOI: 10.1080/00958972.2011.634909
Copper(II) complex based on a V-shaped ligand, 2,6- bis (2-benzimidazolyl)pyridine: synthesis, crystal structure, DNA-binding properties, and antioxidant activitiesJournal of Coordination Chemistry, 2011, 64(24), 4383-4396. DOI: 10.1080/00958972.2011.640934
A substitution product generated from a Mn-p-ferrocenylbenzoate precursor: synthesis, crystal structure and propertiesJournal of Coordination Chemistry, 2008, 61(13), 2105-2112.
A structure and magnetic properties of one-dimensional manganese/cobalt coordination polymers with 5-nitro-1,3-benzenedicarboxylic acid and imidazoleJournal of Coordination Chemistry, 2008, 61(13), 2150-2156.
Solvothermal synthesis, structure and properties of two new compounds based on Keggin polyoxometalates decorated by copper complexesJournal of Coordination Chemistry, 2008, 61(23), 3753-3762. DOI: 10.1080/00958970802120192
Synthesis and magnetic characterization of Ln(III)-Co(II) complexes with 1,10-phenanthroline ligandsJournal of Coordination Chemistry, 2009, 62(5), 808-816. DOI: 10.1080/00958970802308367
Synthesis, structure, and properties of a 1-D copper(II) complex with nitronyl nitroxide radicalsJournal of Coordination Chemistry, 2009, 62(13), 2076-2085. DOI: 10.1080/00958970902756457
Synthesis, crystal structure and magnetism of [Mn(tfbdc)(MeOH)4] (tfbdc = tetrafluoroterephthalate)Journal of Coordination Chemistry, 2009, 62(15), 2449-2456. DOI: 10.1080/00958970902838347
Two spin systems based on [Ni(dmit)2]- building blocks exhibiting 1-D chain and 2-D sheet structures: crystal structures and magnetic propertiesJournal of Coordination Chemistry, 2009, 62(23), 3772-3781. DOI: 10.1080/00958970903159149
Synthesis, structure, and magnetic properties of a self-assembled salicylaldimine neodymium(III) nitrate coordination polymerJournal of Coordination Chemistry, 2010, 63(1), 106-114. DOI: 10.1080/00958970903302699
A transition-metal-templated 3-D supramolecular framework based on molybdenum-vanadium polyoxoanionsJournal of Coordination Chemistry, 2010, 63(3), 394-405. DOI: 10.1080/00958970903469704
Synthesis, crystal structure, and magnetic properties of a new end-to-end thiocyanato-bridged dicobalt(II) complex CoII(dien)(H2O)(NCS)(μ1,3-NCS)CoII(dien)(NCS)2 (dien = diethylenetriamine)Journal of Coordination Chemistry, 2010, 63(4), 610-616. DOI: 10.1080/00958970903586259
A dinuclear nickel(II) complex with dissimilar bridges: synthesis, crystal structure, and magnetic characterizationJournal of Coordination Chemistry, 2010, 63(5), 801-808. DOI: 10.1080/00958971003657677
Constructing porous lanthanide coordination polymers of 4,4`-bipyridine-N,N`-dioxide templated by single- and double-Keggin anionsJournal of Coordination Chemistry, 2008, 61(23), 3800-3814. DOI: 10.1080/00958970802123469
A new 3D polyoxometalate based on saturated Wells-Dawson polyanions and calcium cationsJournal of Coordination Chemistry, 2008, 61(22), 3651-3658. DOI: 10.1080/00958970802105060
Synthesis, structure and properties of rare earth substituted germanotungstates: Pr/[α-GeW11O39]Journal of Coordination Chemistry, 2008, 61(21), 3467-3475. DOI: 10.1080/00958970802068870
Three porous coordination polymers of Co2+ and dpdo ligands with channels hosting polyanion chainsJournal of Coordination Chemistry, 2009, 62(12), 1989-2002. DOI: 10.1080/00958970902744982
A water chain with trimeric/hexameric clusters trapped in a POM/Ln compoundJournal of Coordination Chemistry, 2010, 63(3), 418-425. DOI: 10.1080/00958970903474225
Hydrothermal syntheses and characterizations of two compounds assembled from tungstates and bpy (bpy = 4,4'-bipyridine)Journal of Coordination Chemistry, 2010, 63(3), 426-434. DOI: 10.1080/00958970903509269
Polyoxotungstate clusters: syntheses, characterization, and crystal structures of [CuII(1,3-dap)2]2[CuII(1,3-dap)]2H[α-PW10.5CO40] and [CuI(phen)2]3[α-PW12O40]Journal of Coordination Chemistry, 2010, 63(9), 1463-1472. DOI: 10.1080/00958972.2010.483728
A new layered vanadate complex with a tunnel structure: [{Cu(mbpy)}2V8O21] (mbpy = 4,4'-dimethyl-2,2'-bipyridine)Journal of Coordination Chemistry, 2010, 63(10), 1690-1699. DOI: 10.1080/00958972.2010.490295
Hydrothermal synthesis and characterization of a new Anderson-type polyoxometalateJournal of Coordination Chemistry, 2011, 64(13), 2388-2398. DOI: 10.1080/00958972.2011.598230
Olefin epoxidation with tert-BuOOH catalyzed by vanadium polyoxometalate immobilized on ionic liquid-modified MCM-41Journal of Coordination Chemistry, 2011, 64(23), 4134-4144. DOI: 10.1080/00958972.2011.636038