Evidence for the Formation of a Covalent Thiosulfinate Intermediate with Peroxiredoxin in the Catalytic Mechanism of Sulfiredoxin

Xavier Roussel, Guillaume Bechade, Alain Van Dorsselaer, Sarah Sanglier-Cianferani, Guy Branlant and Sophie Rahuel-Clermont

The Journal of Biological Chemistry 283 ( 33 ): 22371 - 22382 , 2008